It's any easy calculation to make, if you can accurately estimate the value of the stored usable energy (which is around 85% to 90% of the charge energy). Taking the PW2 as an example, it has a usable energy of 13.5 kWh, and takes a bit over 15 kWh of charge to get that usable capacity. Unless you have a large PV array, then the PW2 won't charge from PV for a fair bit of the year. For example, our 6.25 kWp array is averaging about 3 kWh per day of excess generation right now, perhaps 20% of the excess generation capacity needed to charge a PW2. That means we'd only charge a PW2 up to capacity once every five days on average at this time of the year.
After 5 days of charging from excess PV generation we'd get about £2.20 worth of usable energy back out of the PW2. This would improve markedly as the summer approaches, but our electricity demand also drops a great deal at the same time. By April we'd not be able to use more than about 1/3rd of a PW2 battery capacity, despite it being charged pretty much every day, simply because our electricity consumption during the night would be lower, and it makes more sense to utilise excess PV generation during the day for loads that we'd otherwise put on at night (saves the battery round-trip losses).
To just recover the capital investment of £6.5k in a PW2 installation, you would need to be able to use about 40 MWh of stored excess PV generation electricity from it at current prices before the PW2 dies of old age. We've used a total of 10 MWh in the last 5 years, so even if we could use all of the capacity in a PW2 then it would still take 20 years just to recover the capital investment. I doubt that the calendar life of the cells would extend more than about 15 years at the very most, and my experience with my 9 year old electric motorcycle battery pack is that calendar life ageing has been significantly greater than cycle life ageing, as that pack is now down to about 50% of it's original capacity, after around 600 cycles.
If you are able to use close to the 13.5 kWh capacity of the PW2 every day, and more importantly, are able to charge it from excess PV generation to full capacity every day (which probably needs a PV array of 20 kWp or more at a guess), then yes, it will probably recover the original capital investment within about 12 years or so, around the same as the payback for a PV installation, perhaps.